Environment variable troubles

[WENDEL.MASON]

Well, I need to add a new environment variable to PATH and I have tried to do so through the GUI and PowerShell command lines. However even after I've done this PowerShell and Cmd both can't find the variable and end up redirecting me to the Microsoft store. The variable is a python executable for further elaboration. The path does show up in the PATH environment variables GUI but for whatever reason the system can't find it. Any help is greatly appreciated.

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